| .THE INFLUENCE OF AXIALLIGANDS ON THE ELECTRONIC ABSORPTION SPECTRA OF PHTHALOCYANINATOIRON(Ⅱ)[J].分子催化,1989,(Z1): |
| THE INFLUENCE OF AXIALLIGANDS ON THE ELECTRONIC ABSORPTION SPECTRA OF PHTHALOCYANINATOIRON(Ⅱ) |
|
| |
| DOI： |
| 中文关键词: |
| 英文关键词: |
| 基金项目: |
|
|
| 摘要点击次数: 835 |
| 全文下载次数: 15 |
| 中文摘要: |
| Axial ligation in solution by phthalocyaninatolron(Ⅱ)with a varicty of donor ligandshas been widely investigated by measuring the visible spectral changes.It has been foundthat the axial ligation does not influence the Q_ο-οband so much as the Ⅱ-band,the appearance and the red shift of the latter under the action of σ-donation of ligands could be attri-buted to the Charge transfer from the metal d-orbital toward e_σ(π)orbital of PC-ring:e_g(dπ)M→Cg(π)Pc.A linear relation was found to exist between the energy of Q_ο-οand that of Ⅱ-band of ligands containing the same donor atoms(O,N,S,).This may be corre-lated with the electronegativity of donoratoms. |
| 英文摘要: |
| |
| HTML 查看全文 查看/发表评论 下载PDF阅读器 |
|
|
|
