| 燕远勇,左焕培.新型水溶性膦铑络合物催化烯烃的氢甲酰化反应研究[J].分子催化,1994,(2):147-150 |
| 新型水溶性膦铑络合物催化烯烃的氢甲酰化反应研究 |
| New Type Water-Soluble Phosphine Rhodium Complexes Catalyzed Hydroformylation Reaction |
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| DOI： |
| 中文关键词: 烯烃 膦 铑 络合物 催化剂 |
| 英文关键词:Olefines,Water-soluble phosphine rhodium complex catalyst,Hydroformylation,Aldehyde., |
| 基金项目:国家自然科学基金 |
| 燕远勇 左焕培 |
| 大连理工大学化工学院 |
| 摘要点击次数: 1117 |
| 全文下载次数: 16 |
| 中文摘要: |
| 新型水溶性膦铑络合物催化烯烃的氢甲酰化反应研究燕远勇，左焕培，金子林（大连理工大学化工学院，大连１１６０１２）关键词烯烃，水溶性膦铑络合催化剂，氢甲酰化，醛．１．前言为克服催化剂的流失和与反应产物的分离困难，近年来均相催化的一个重要进展是开发了以磺化... |
| 英文摘要: |
| A new type water-soluble phosphine including p(CH2CH2O)nH]3(n=3-14)was prepared and their rhodium complexes formed in situ were used in two-phase system hydroformylation of 1-hexene to 1-dodecene This type of surfactant complex ligand gives rise to good catalytic activity and selectivity for the biphasic hydroformylation of higher olefines.The best yield(85%)in this rhodium-catalyzed biphasic hydroformylation of 1-dodecene is obtained. The influences of reaction conditions have also been studied. |
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