马春曦,王宝辉.钙钛矿型CO氧化催化剂耐SO2中毒性质的研究[J].分子催化,1997,(1):59-62 |
钙钛矿型CO氧化催化剂耐SO2中毒性质的研究 |
A Study on SO 2 Poisoning Properties of Perofskite ABO 3 and ABO 3/CaO for CO Oxidation |
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DOI: |
中文关键词: 钙钛矿型 一氧化碳 氧化 硫中毒 催化剂中毒 |
英文关键词:Perofskite, CO oxidation, Sulfur poisoning |
基金项目: |
马春曦 王宝辉 |
大庆石油学院石油化工系 |
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中文摘要: |
钙钛矿型CO氧化催化剂耐SO2中毒性质的研究马春曦王宝辉(大庆石油学院石油化工系安达151400)关键词钙钛矿型催化剂一氧化碳氧化硫中毒近年来,人们对钙钛矿型复合物CO氧化催化剂作了大量研究,证明其具有很高的CO氧化活性[1-3],并开始尝试应用于汽... |
英文摘要: |
Perofskite ABO 3, ABO 3/CaO(A=La,Sr, B=Fe,Co)catalysts were prepared by the impregnation and decomposition of the salts. The sulfur resistant properties and mechanism in the CO oxidation were studied using IR and fix bed micro reactor with a continuous SO 2 flow. The results show that the catalysts were poisoned by SO 2 to a certain extent in the low temperature while the supported ABO 3/CaO samples possess a high sulfur resistant property. According to these observations, the poisoning mechanism is discussed. |
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