| 周继承,王祥生.无机钛硅原料体系合成TS-1催化丙烯环氧化反应[J].分子催化,2000,(5):363-368 |
| 无机钛硅原料体系合成TS-1催化丙烯环氧化反应 |
| Study on the Epoxidation of Propylene Catalyzed by TS-1 Synthesized from Inorganic Titanosilicate System |
| 修订日期：2000-03-20 |
| DOI： |
| 中文关键词: 钛硅分子筛 TS－1 催化剂 丙烯环氧化 环氧丙烷 |
| 英文关键词:Titanium silicalites,Molecular sieves,TS\|1,Inorganic titanosilicate system,Propylene epoxidation |
| 基金项目:国家自然科学基金!重大项目 (编号 2 9792 0 70 ) |
| 周继承 王祥生 |
| [1]湘潭大学化学化工学院化工系,湘潭 [2]大连理工大学碳资源综合利用开放实验室,大连 |
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| 中文摘要: |
| 研究了无机钛硅原料体系合成的ＴＳ－１催化丙烯环氧化的反应，并与经典法、修正法制得样品的催化性能进行了比较。考察了搅拌、Ｎａ２ＣＯ３加入量、反应时间、反应温度、双氧水加量、催化剂量及溶剂等对丙烯环氧化反应的转化率、选择性等的影响，并初步探讨了无机钛硅原料合成的ＴＳ－１的再生性能。结果表明，对于丙烯环氧化反应，无机钛硅原料合成ＴＳ－１样品与经典法和修正法制取样品的催化性能相当；反应条件对丙烯环氧化反应 |
| 英文摘要: |
| The epoxidation of propylene catalyzed by TS\|1 synthesized from inorganic titanosilicate system was studied, and the catalytic performances of TS\|1 samples synthesized from inorganic titanosilicate system, by convention method and by the modified method were compared. Effects of stirring, amount of Na\-2CO\-3 solution, reaction time, reaction temperature, amounts of H\-2O\-2, amount of catalyst and solvent on the conversion of H\-2O\-2 and selectivity to propylene oxide were investigated. Regeneration of catalyst synthesized from inorganic titanosilicate system was also investigated. The experimental results show that three samples possess nearly the same high catalytic activity for the epoxidation of propylene. The epoxidation of propylene is greatly affected by reaction conditions: the addition of Na\-2CO\-3 solution and the amount added have significant effect on the selectivity of propylene oxide and the effect of solvent on epoxidation of propylene is also obvious. When methanol is used as the solvent, propylene glycol and its monomethyl ethers are the main by\|products. |
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