| 许国强,黄雪红.丙烯酰胺—丙烯酸十四酯共聚物镍配合物的结构及催化性能[J].分子催化,2001,(1):61-65 |
| 丙烯酰胺—丙烯酸十四酯共聚物镍配合物的结构及催化性能 |
| Research on Structure of Acrylamide Tetradecyl Acrylate Copolymer Nickel Complexes and its Catalytic Performance |
| 修订日期：2000-05-08 |
| DOI： |
| 中文关键词: 丙烯酰胺－丙烯酸＋四酯共聚物 镍配合物 催化性能 聚甲基丙烯酸甲酯 催化聚合 催化剂 |
| 英文关键词:Acryamide tetradecyl acrylate copolymer,Ni complex,Catalytic property,Methyl methacrylate |
| 基金项目:福建省自然科学基金资助项目! (B970 12 ) . |
| 许国强 黄雪红 |
| 福建师范大学高分子研究所!福建福州350007 |
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| 中文摘要: |
| 合成了一系列丙烯酰胺－丙烯酸＋四酯共聚物镍配合物；采用ESR、XPS、 IR、DTA－TG和电导率法，研制了其中存在的配位结构。通过镍配合物催化甲基丙烯酸甲酯的聚合反应，考察了它们的催化性能，并证明了该催化剂具有高活性和低污染性。 |
| 英文摘要: |
| A series of acrylamide tetradecyl acrylate copolymer nickel complexes were synthesized. Using ESR, XPS, IR, DTA TG fechniques and specific conductivity measurement, the coordination units in the complexes were studied. Their catalytic properties in polymerization of MMA were also examined. Experimental results reveal that these complexes possess high catalytic activity and low pollution. |
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