| 吴玉琪,吕功煊.几种低碳醇在Pt／TiO2上的光催化产氢速率的研究[J].分子催化,2001,(6):467-470 |
| 几种低碳醇在Pt／TiO2上的光催化产氢速率的研究 |
| H2 Production Rate of Several Lower Alcohols in Photocatalytic Reforming on Pt/TiO2 Catalyst |
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| DOI： |
| 中文关键词: 低碳醇 Pt／TiO2 光催化 产氢速率 铂 二氧化钛 负载型光催化剂 氢气 制备 |
| 英文关键词:Alcohol,Hydrogen production,Pt/TiO\-2, Photocatalytic reforming |
| 基金项目:国家重点基础研究发展计划(973计划)，G200000264， |
| 吴玉琪 吕功煊 |
| [1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室，甘肃兰州730000 [2]中国科学院兰州化学物理研 |
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| 中文摘要: |
| 主要考察了无氧条件下低碳醇（甲、乙、丙醇）在Pt/TiO2表面光催化重整反应制氢。深入探讨了几种低碳醇与其放氢速率的构-效关系，提出了低碳醇在Pt/TiO2光催化剂表面吸附态的模型。 |
| 英文摘要: |
| Hydrogen production rates in anaerobic photocatalytic reforming of several lower alcohols (methanol, ethanol, n \|propanol, isopropanol) on Pt/TiO\-2 catalyst in aqueous solution have been studied. The relation between the hydrogen production rate and molecule structure of alcohols on Pt/TiO\-2 catalyst was discussed in details. XPS and TPD techniques were used to characterize the catalyst and to investigate the states of adsorbed alcohols. A possible model of alcohol adsorption states on the surface of TiO\-2 is proposed. |
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