| 照日格图,李文钊,KIEFFER Roger.丙烷氧化脱氢氧化物催化剂的活性氧物种[J].分子催化,2002,(4):279-283 |
| 丙烷氧化脱氢氧化物催化剂的活性氧物种 |
| Active Oxygen Species of Oxide Catalysts in Propane Oxidative Dehydrogenation |
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| DOI： |
| 中文关键词: 丙烷 氧化脱氢 氧化物催化剂 活性氧物种 催化性能 半导体催化剂 |
| 英文关键词:Propane,Oxidative dehydrogenation,Oxide catalyst,Active oxygen species |
| 基金项目: |
| 照日格图 李文钊 KIEFFER Roger |
| [1]内蒙古师范大学化学系，内蒙古呼和浩特010022 [2]中国科学院大连化学物理研究所，辽宁大连116023 |
| 摘要点击次数: 1293 |
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| 中文摘要: |
| 研究了半导体金属氧化物催化剂丙烷氧化脱氧制丙烯的性能，发现p-型半导体金属氧化物有低温催化性能，n-型半导体金属氧化物有高温催化性能，H2－TPR，O2－TPD－MS和原位电导研究结果表明，p-型半导体金属氧化物的活性氧物种为非化学计量氧物种，n-型半导体的活性氧物种为表面晶格氧。 |
| 英文摘要: |
| In this paper, the catalytic activity of semiconductor metal oxides for propane oxidative dehydrogenation was investigated. It was found that p\|type semiconductor metal oxides showed low temperature catalytic properties and n\|type ones revealed high temperature catalytic behaviors. H\-2\|TPR, O\-2\|TPD\|MS and in situ electrical conductivity studies confirmed that the active oxygen species of p\|type semiconductor catalysts were nonstoichiometric oxygen species and the ones of n\|type catalysts were surface lattice oxygen. |
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