朱向学,李朝恒,刘淑文,徐贤伦.过氧化氢生产用铂催化剂的制备及性能研究[J].分子催化,2002,(5):359-363 |
过氧化氢生产用铂催化剂的制备及性能研究 |
Preparation and Catalytic Properties of Supported Platinum Catalysts for Hydrogen Peroxide Production of AQ Process |
修订日期:2002-01-16 |
DOI: |
中文关键词: 生产 制备 蒽醌法 过氧化氢 铂催化剂 氢化 催化性能 |
英文关键词:Anthraquinone process,Hydrogen peroxide,Pt catalyst,Hydrogenation |
基金项目: |
朱向学 李朝恒 刘淑文 徐贤伦 |
中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室 甘肃兰州730 |
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中文摘要: |
用浸渍法制备了过氧化氢生产用蒽醌加氢负载型铂催化剂,考察了载体的预处理温度、不同氧化物载体、铝钛复合载体中TiO2的含量以及La、Ce助剂对催化剂性能的影响;用BET法测定了催化剂的表面积;采用H2-O2滴定法测定Pt的分散度,并在固定床反应器上考察了催化剂的性能。结果发现,用经1223K焙烧过的载体及在Al2O3载体中引入10%-20%TiO2,并引入一定量La、Ce助剂所制备的催化剂,具有良好的活性和稳定性,因而具有较好的工业应用前景。 |
英文摘要: |
Supported Platinum catalysts for alkylanthraquinone hydrogenation were prepared by impregnation method. The influence of calcination temperature of supports, various supports, the content of TiO\-2 in Al\-2O\-3\|TiO\-2 and La or Ce additive on the catalysts' property were studied, as well as the surface of the catalysts was determined by BET method and the Pt dispersion was determined by H\-2\|O\-2 titration. The results showed that catalysts supports' calcination temperature at 1 223 K, Al\-2O\-3\|TiO\-2 support contenting 10%~20% TiO\-2 and the additive of La or Ce were of benefit to the catalytic properties and the catalysts had a better prospect of industrialization. |
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