| 赵睿,张汉鹏,许珊,王晓来,索继栓.SiO2包裹的杂多酸催化剂Cu-H4SiW12O40瞬间催化四氢吡喃化反应[J].分子催化,2003,(6):414-416 |
| SiO2包裹的杂多酸催化剂Cu-H4SiW12O40瞬间催化四氢吡喃化反应 |
| An Instantaneous Approach to Tetrahydropyranylation of Alcohols Using Silica-impregnated Cu-H4SiW12O40 Catalyst |
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| DOI： |
| 中文关键词: Cu—H4SiW12O40 四氢吡喃化反应 微乳化技术 催化剂 |
| 英文关键词:Cu-H_4SiW_(12)O_(40),Tetrahydropyranylation,Reverse microemulsion,Catalyst |
| 基金项目: |
| 赵睿 张汉鹏 许珊 王晓来 索继栓 |
| 中国科学院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,甘肃,兰州730000 |
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| 全文下载次数: 19 |
| 中文摘要: |
| 以微乳化法制备的二氧化硅担载的的杂多酸催化剂Cu—H4SiW12O40在室温下能瞬间催化四氢吡喃化反应。且催化剂在至少重复使用四次而未见明显的失活。 |
| 英文摘要: |
| Silica-impregnated Cu-H4SiW12O40 was found to be an efficient heterogeneous catalyst for the tetrahydropyranylation of alcohols. The reaction was very quickly (within 5 second) and the catalyst could be reused for at least 4 times without obviously lowering of its activity. |
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