| 尚洁,赵文军.乙酸中碘催化氧化苄醇为相应醛或酮[J].分子催化,2010,(5):0 |
| 乙酸中碘催化氧化苄醇为相应醛或酮 |
| Iodine-catalyzed aerobic oxidation of alcohols to corresponding aldehydes or ketones in acetic acid |
| 投稿时间：2010-04-30 修订日期：2010-07-21 |
| DOI： |
| 中文关键词: 碘，4-OH-TEMPO，苄醇，空气 |
| 英文关键词:Iodine, 4-OH-TEMPO, benzyl alcohol, air |
| 基金项目:中国新疆自治区国家自然科学基金 |
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| 中文摘要: |
| 本文报道了用I2/NaNO2/4-OH-TEMPO为催化剂，空气为氧化剂，在冰乙酸中催化氧化苄醇的方法。文中考察了催化剂各组分和温度对催化氧化反应的影响，在催化过程中碘替代过渡金属作为4-OH-TEMPO的共催化剂，在选择条件下苄醇氧反应的转化率和选择性效果良好，产率达到90%。 |
| 英文摘要: |
| An efficient aerobic oxidation of alcohols to corresponding aldehydes or ketones catalyzed by the system of I2/NaNO2/4-OH-TEMPO in acetic acid has been developed. The influence of each component and the amount of catalyst were studied. Iodine instead of metal is co-catalyst in the procedure. The conversion and the selectivity are high and the yield reached 90% under optimum conditions. |
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