| 吴从意.1,3-丙二醇制备研究进展[J].分子催化,2012,(3):276-283 |
| 1,3-丙二醇制备研究进展 |
| Progress in the Synthesis of 1,3-Propanediol |
| 投稿时间：2012-03-29 修订日期：2012-04-25 |
| DOI： |
| 中文关键词: 1,3-丙二醇 3-羟基丙醛 发酵法 甘油 加氢 |
| 英文关键词:1,3-propanediol 3-hydroxypropanal fermentation glycerol hydrogenation |
| 基金项目:国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 中文摘要: |
| 1,3-丙二醇作为一种重要的化工原料，正得到越来越多的关注，其制备正成为一个研究热点。除了环氧乙烷羰基化法、丙烯醛水合加氢法和微生物发酵法等传统的制备方法以外，3-羟基丙酸甲酯加氢和甘油选择性氢解制备1,3-丙二醇作为新的制备手段正在得到人们的重视。本文综述了1,3-丙二醇制备的研究进展，分析了存在的问题和可能的解决途径，并对未来做了展望。 |
| 英文摘要: |
| As an important chemical raw materials, 1,3-propanediol has been paid ever increasing attention, and much effort has been made. In addition to classical preparation methods such as hydration of acrolein, hydroformylation of ethylene oxide to 3-hydroxypropanal followed by hydrogenation, and the fermentation of polyol by microbial to 1,3-propanediol, hydrogenation of methyl 3-hydroxypropionate and selective hydrogenolysis of glycerol to 1,3-propanediol as novel alternative routes has been focus. In this paper, the present status and research advances on preparation of 1,3-propanediol were reviewed. Moreover, the development trends and future were also discussed based on the previous work. |
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