| 曾祥华.CuCl/I2催化末端烯烃与磺酰氯反应合成烯基砜类化合物研究[J].分子催化,2013,(3):199-204 |
| CuCl/I2催化末端烯烃与磺酰氯反应合成烯基砜类化合物研究 |
| Synthesis of vinyl sulfones from terminal olefins and sulfonyl chloride derivatives catalyzed by copper(I) chloride/I2 |
| 投稿时间：2013-05-08 修订日期：2013-05-19 |
| DOI： |
| 中文关键词: 苯乙烯 氯化亚铜 磺酰氯 碘 |
| 英文关键词:styrene copper(I) chloride sulfonyl chloride iodine |
| 基金项目:国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 中文摘要: |
| 研究了用CuCl/I2催化一系列端基烯烃和磺酰氯反应合成烯基砜类化合物，反应体系中添加催化剂量的分子碘，可以大幅度提高该反应的产率，最高可获得97%的产率。同时，考察了各种铜盐的催化活性以及反应介质对反应的影响。 |
| 英文摘要: |
| A series of vinyl sulfones were synthesized from terminal olefins and sulfonyl chloride derivatives catalyzed by CuCl/I2. Interestingly, addition of catalytic amount of I2 was benefit for improving the yield greatly and the yield of vinyl sulfone was up to 97%. Besides, the activities of several kinds of copper salts and the effect of solvents were investigated. |
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