| 王雨康,吕加营,曹瑜,杨捷,李晶,赵方园.脂肪族羧酸电化学脱羧偶联反应研究进展[J].分子催化(中英文),2025,39(3):273-287 |
| 脂肪族羧酸电化学脱羧偶联反应研究进展 |
| Research Progress in Electrochemical Decarboxylative Coupling Reaction of Aliphatic Carboxylic Acids |
| 投稿时间：2025-03-06 修订日期：2025-03-24 |
| DOI：10.16084/j.issn1001-3555.2025.03.009 |
| 中文关键词: 脂肪族羧酸 电化学脱羧 金属催化 |
| 英文关键词:aliphatic carboxylic acids electrochemical decarboxylation metal catalysis |
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| 中文摘要: |
| 电化学脱羧偶联反应作为一种绿色、高效的有机合成方法, 近年来受到广泛关注. 本文综述了电化学脱羧反应在构建C―C、C―N、C―O和C―X键方面的最新研究进展, 重点介绍了金属催化下的电化学脱羧反应机制, 详细阐述了自由基介导、碳正离子机理以及光电协同催化等关键反应过程, 同时展示了该反应在复杂分子合成中的应用潜力. 文章还探讨了电化学脱羧反应的优势和局限性, 同时对该领域当前所面临的挑战及未来可能的发展方向进行了展望. |
| 英文摘要: |
| Electrochemical decarboxylative coupling reaction, as a green and efficient organic synthesis method, has received extensive attention in recent years. In this paper, the latest research progress of the electrochemical decarboxylation reaction in the construction of C―C, C―N, C―O and C―X bonds is reviewed. The mechanism of metal-catalyzed electrochemical decarboxylation reaction is emphatically introduced. The key reaction processes such as radical-mediated, carbocation mechanism and electrophoto synergistic catalysis are elaborated in detail. At the same time, the application potential of this reaction in the synthesis of complex molecules is demonstrated. The advantages and limitations of electrochemical decarboxylation are also discussed. At the same time, the current challenges and possible future development directions in this field are prospected. |
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